Cathode properties of metal trifluorides in Li and Na secondary batteries

被引：157

作者：

Nishijima, Manabu ^{[1
]}

Gocheva, Irina D. ^{[1
]}

Okada, Shigeto ^{[1
]}

Doi, Takayuki ^{[1
]}

Yamaki, Jun-ichi ^{[1
]}

Nishida, Tetsuaki ^{[2
]}

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan

[2] Kinki Univ, Sch Humanity Oriented Sci & Engn, Iizuka, Fukuoka 8208555, Japan

来源：

JOURNAL OF POWER SOURCES | 2009年 / 190卷 / 02期

关键词：

Metal trifluoride; Perovskite; Na secondary battery; RECHARGEABLE LITHIUM BATTERIES; FLUORIDE NANOCOMPOSITES; SODIUM; INSERTION;

D O I：

10.1016/j.jpowsour.2009.01.051

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fluorine compounds have high discharge voltage due to its highly ionic metal-ligand bonds. In them, perovskite-type metal trifluorides with corner sharing matrix have large bottlenecks of diffusion pathways for intercalants. iron trifluoride composites (FeF3-C) prepared by planetary ball milling with carbon showed reversible charge/discharge behavior not only for Li, but also for Na anodes. X-ray diffraction and Fe-57 Mossbauer spectroscopy were applied to characterize the electrochemical properties of FeF3 vs. Li and Na anodes. The cathode performances of the other commercially available transition metal trifluorides such as MF3 (M =Ti, V, Mn, Co) have been also investigated. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：558 / 562

页数：5

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