Synthesis and spectroscopic characterization of binuclear thioazomethine palladacycles

被引：18

作者：

Chattopadhyay, P ^{[1
]}

Nayak, MK ^{[1
]}

Bhattacharyya, SP ^{[1
]}

Sinha, C ^{[1
]}

机构：

[1] UNIV BURDWAN GOLAPBAG,DEPT CHEM,BURDWAN 713104,W BENGAL,INDIA

来源：

POLYHEDRON | 1997年 / 16卷 / 08期

关键词：

thioazomethines; cyclopalladation; dinuclear;

D O I：

10.1016/S0277-5387(96)00422-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several 1,2-bis(2-thio(N-benzylidene)anilines)ethane [(RC(6)H(4)CH = NC6H4SCH2)(2)] (4) and 1,3-bis(2-thio(N-benzylidene)anilines)propane [(RC(6)H(4)CH = NC6H4SCH2)(2))(2)CH2] (5), R = H (a), 11-CH3 (b), 11-OCH3 (c), 11-Cl (d) and 11-NO2 (e)] have been synthesized and reacted with Pd(OAc)(2) in boiling benzene. The binuclear cyclopalladated acetato complexes (8/9) thus obtained reacted with LiCl, giving the chloro complexes having the coordination sphere [Pd(C,N,S)Cl-2](2) (10/11). The mod of ligand binding was established using high-resolution H-1 NMR and IR data. Copyright (C) 1997 Elsevier Science Ltd.

引用

页码：1291 / 1295

页数：5

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