Atomically Efficient Synthesis of Self-assembled Monodisperse and Ultrathin Lanthanide Oxychloride Nanoplates

被引：83

作者：

Du, Ya-Ping

Zhang, Ya-Wen ^{[1
]}

Sun, Ling-Dong

Yan, Chun-Hua

机构：

[1] Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 09期

关键词：

CORE/SHELL NANOPARTICLES; NANOCRYSTALS; IONS; SUPERLATTICES; SURFACE; PHASE; CORE;

D O I：

10.1021/ja8095416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monodisperse and ultrathin LaOCl nanoplates were synthesized via the thermolysis of La(CCl3COO)(3) in long chain amine and 1-octadecene. This single source precursor approach is simple but atomically efficient. The uniform amine-capped LaOCl nanoplates can be aligned into nanowire-like and nanorod-like superstructures, as a result of the different strengths of the interchain molecular interactions of the capping molecules during the self-assembly process of the nanoplates.

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页码：3162 / +

页数：3

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