Adsorption of carbon dioxide by X zeolites exchanged with Ni2+ and Cr3+:: isotherms and isosteric heat

The adsorption of CO2, at intervals of 30 K from 303 K was carried out on Mn+X zeolites (Mn+ = Ni2+ or Cr3+) exchanged at different degrees. The structural regularity of the zeolite lattice of NaX and the existence of well-defined cavities within which the adsorbate molecules are lodged suggest that it should be possible to use various isotherm equations. Several models were thus used to describe the experimental isotherms. The best fit of adsorption isotherm data is obtained with the Sips model. The Volmer model also describes satisfactorily the isotherms of CO2 adsorption by NaX, Ni(x)X, and Cr(x)X. Analysis of the isosteric heat reveals a character energetically heterogeneous for NaX and Ni(x)X samples exchanged at a higher degree of Ni2+ exchange and at low coverage. Specific interaction is also obtained between the adsorbate molecules and Cr(x)X exchanged at a lower degree. From these considerations, hypotheses will be advanced to describe the behavior of the adsorbed phase within zeolitic cavities. (C) 2004 Elsevier Inc. All rights reserved.