Iron-Catalyzed Hydrogenation, Hydride Transfer, and Hydrosilylation: An Alternative to Precious-Metal Complexes?

被引:228
作者
Gaillard, Sylvain [1 ]
Renaud, Jean-Luc [1 ]
机构
[1] Ecole Natl Super Chim Rennes, UMR 6226, F-35700 Rennes, France
关键词
homogeneous catalysis; hydride transfer; hydrogenation; iron; reduction;
D O I
10.1002/cssc.200800071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The dawn of a new iron age? Iron is one of the least expensive and non-toxic metals, however, its chemistry has remained less studied than that of precious metals. Recent advances in reduction chemistry using iron complexes as catalysts are reviewed and the great potential of this cheap but chic metal is illustrated in this Highlight. © 2008 Wiley-VCH Verlag GmbH & Co.KGaA, Weinheim.
引用
收藏
页码:505 / 509
页数:5
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