Direct reductive amination of carbonyl compounds with primary/secondary amines using recyclable water-soluble FeII/EDTA complex as catalyst

被引：74

作者：

Bhor, Malhari D. ^{[1
]}

Bhanushali, Mayur J. ^{[1
]}

Nandurkar, Nam S. ^{[1
]}

Bhanage, Bhalchandra M. ^{[1
]}

机构：

[1] Univ Mumbai, Dept Chem, Inst Chem Technol, Bombay 400019, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 06期

关键词：

water-soluble catalyst; imines; hydrogenation; biphasic catalysis;

D O I：

10.1016/j.tetlet.2007.12.023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct reductive amination of aliphatic, aromatic and heterocyclic carbonyl compounds with primary/secondary amines is reported with water-soluble Fe(II)/EDTA complex as a catalyst using low-pressure molecular hydrogen in a biphasic media. The catalyst is highly selective, recyclable and is an excellent replacement for expensive noble metal catalysts or stoichiometric reducing agents. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：965 / 969

页数：5

共 38 条

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