Synthesis, characterisation and reactivity of novel bis(tosyl)imidoruthenium(VI) porphyrin complexes; X-ray crystal structure of a tosylamidoruthenium(IV) porphyrin

被引：66

作者：

Au, SM

Fung, WH

Cheng, MC

Che, CM

Peng, SM

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 17期

关键词：

D O I：

10.1039/a702093g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(tosyl)imidoruthenium(VI) porphyrin complexes are prepared and characterised by spectroscopic means; [Ru-VL(tpp)(NTs)(2)] can undergo imido group transfer reactions with alkenes to afford aziridines, as well as C-H bond oxidation of benzyl alcohol to give benzaldehyde; a tosylamido ruthenium(IV) complex is also isolated and characterised by X-ray diffraction.

引用

页码：1655 / 1656

页数：2

共 16 条

[11] Synthesis and reactivities of (arylsulfonyl)amido complexes of ruthenium(II) [J].