Raman scattering in BIMEVOX (ME = Mg, Ni, Cu, Zn) single crystals

被引：16

作者：

Bacewicz, R ^{[1
]}

Kurek, P ^{[1
]}

机构：

[1] Warsaw Univ Technol, Inst Phys, PL-00662 Warsaw, Poland

来源：

SOLID STATE IONICS | 2000年 / 127卷 / 1-2期

关键词：

BIMEVOX; vanadium compounds; Raman scattering; crystal structure;

D O I：

10.1016/S0167-2738(99)00262-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Raman spectra of BIMEVOX (ME = Mg, Ni, Cu, Zn) single crystals are reported. The main features of the spectra observed in the 600 to 900 cm(-1) frequency range are assigned to the stretching vibrations of the V-O bonds. Interpretation of the Raman spectra is based on the diatomic approximation and the correlation between the frequencies of stretching vibrations of vanadium-oxygen bonds and bond lengths. V-O bond orders are determined from an empirical relation between these frequencies and bond orders. The results point to predominantly tetrahedral coordination of vanadium in the studied BIMEVOX systems. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：151 / 156

页数：6

相关论文

共 14 条

[1] VIBRATIONAL-SPECTRA AND VALENCE FORCE-FIELD OF CRYSTALLINE V2O5 [J].

ABELLO, L ;

HUSSON, E ;

REPELIN, Y ;

LUCAZEAU, G .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1983, 39 (07) :641-651

[2] THE BIMEVOX SERIES - A NEW FAMILY OF HIGH PERFORMANCES OXIDE ION CONDUCTORS [J].

ABRAHAM, F ;

BOIVIN, JC ;

MAIRESSE, G ;

NOWOGROCKI, G .

SOLID STATE IONICS, 1990, 40-1 (pt 2) :934-937

[3] Effects of preparation parameters on oxygen stoichiometry in Bi4V2O11-δ [J].

Abrahams, I ;

Bush, AJ ;

Krok, F ;

Hawkes, GE ;

Sales, KD ;

Thornton, P ;

Bogusz, W .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (05) :1213-1217

[4] Defect structure of quenched γ-BINIVOX [J].

Abrahams, I ;

Nelstrop, JAG ;

Krok, F ;

Bogusz, W .

SOLID STATE IONICS, 1998, 110 (1-2) :95-101

[5] Defect structure of quenched gamma-BICOVOX by combined X-ray and neutron powder diffraction [J].

Abrahams, I ;

Krok, F ;

Nelstrop, JAG .

SOLID STATE IONICS, 1996, 90 (1-4) :57-65

[6] VIBRATIONAL-SPECTRUM OF SR2V2O7 AND VIBRATIONAL PROPERTIES OF DIVANADATE ION [J].

BARAN, EJ ;

BOTTO, IL ;

PEDREGOSA, JC ;

AYMONINO, PJ .

MONATSHEFTE FUR CHEMIE, 1978, 109 (01) :41-51

[7] EMPIRICAL PARAMETERS FOR CALCULATING CATION-OXYGEN BOND VALENCES [J].

BROWN, ID ;

WU, KK .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (JUL15) :1957-1959

[8] VIBRATIONAL-SPECTRA OF 2 PHASES OF COPPER PYROVANADATE AND SOME SOLID-SOLUTIONS OF COPPER AND MAGNESIUM PYROVANADATE [J].

DEWAAL, D ;

HUTTER, C .

MATERIALS RESEARCH BULLETIN, 1994, 29 (08) :843-849

[9] DETERMINATION OF VANADIUM OXYGEN BOND DISTANCES AND BOND ORDERS BY RAMAN-SPECTROSCOPY [J].

HARDCASTLE, FD ;

WACHS, IE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) :5031-5041

[10] VANADIUM(V) ENVIRONMENTS IN BISMUTH VANADATES - A STRUCTURAL INVESTIGATION USING RAMAN-SPECTROSCOPY AND SOLID-STATE V-51 NMR [J].

HARDCASTLE, FD ;

WACHS, IE ;

ECKERT, H ;

JEFFERSON, DA .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 90 (02) :194-210