A short and efficient synthetic approach to hydroxy (E)-stilbenoids via solid-phase cross metathesis

被引：47

作者：

Chang, S ^{[1
]}

Na, Y

Shin, HJ

Choi, E

Jeong, LS

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, CMDS, Taejon 305701, South Korea

[2] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea

[3] Ewha Womans Univ, Coll Pharm, Seoul 120750, South Korea

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(02)01528-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solid-phase cross metathesis of supported styrenyl ether with styrene derivatives afforded stilbenoids in high yields with complete (E)-selectivity, and this approach could be readily applied for a facile synthesis of a biologically important natural product, resveratrol. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：7445 / 7448

页数：4

共 35 条

[1] Simple synthesis of 5-substituted resorcinols: A revisited family of interesting bioactive molecules [J].

Alonso, E ;

Ramon, DJ ;

Yus, M .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (02) :417-421

[2] Exploiting site-site interactions on solid support to generate dimeric molecules [J].

Blackwell, HE ;

Clemons, PA ;

Schreiber, SL .

ORGANIC LETTERS, 2001, 3 (08) :1185-1188

[3] Precipiton strategies applied to the isolation of α-substituted β-ketoesters [J].

Bosanac, T ;

Wilcox, CS .

TETRAHEDRON LETTERS, 2001, 42 (26) :4309-4312

[4]

Bosanac T, 2001, ANGEW CHEM INT EDIT, V40, P1875, DOI 10.1002/1521-3773(20010518)40:10<1875::AID-ANIE1875>3.0.CO

[5]

2-5

[6]

Choi TL, 2001, ANGEW CHEM INT EDIT, V40, P1277, DOI 10.1002/1521-3773(20010401)40:7<1277::AID-ANIE1277>3.3.CO

[7]

2-5

[8] Polymer-supported catalysis in synthetic organic chemistry [J].

Clapham, B ;

Reger, TS ;

Janda, KD .

TETRAHEDRON, 2001, 57 (22) :4637-4662

[9] HIGHLY SELECTIVE CROSS-METATHESIS OF TERMINAL OLEFINS [J].

CROWE, WE ;

ZHANG, ZJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (23) :10998-10999

[10] Ring opening cross-metathesis on solid support [J].

Cuny, GD ;

Cao, JR ;

Hauske, JR .

TETRAHEDRON LETTERS, 1997, 38 (30) :5237-5240

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