Multilayered Si Nanoparticle/Reduced Graphene Oxide Hybrid as a High-Performance Lithium-Ion Battery Anode

被引:396
作者
Chang, Jingbo [1 ]
Huang, Xingkang [1 ]
Zhou, Guihua [1 ]
Cui, Shumao [1 ]
Hallac, Peter B. [2 ]
Jiang, Junwei [2 ]
Hurley, Patrick T. [2 ]
Chen, Junhong [1 ]
机构
[1] Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53211 USA
[2] Johnson Controls, Power Solut, Global Technol & Innovat, Milwaukee, WI 53209 USA
关键词
LONG CYCLE LIFE; SILICON NANOPARTICLES; RATE CAPABILITY; NANOCOMPOSITE; ELECTRODE; SPECTROSCOPY; CHALLENGES; NANOWIRES; STORAGE; SHEETS;
D O I
10.1002/adma.201302757
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multilayered Si/RGO anode nanostructures, featuring alternating Si nanoparticle (NP) and RGO layers, good mechanical stability, and high electrical conductivity, allow Si NPs to easily expand between RGO layers, thereby leading to high reversible capacity up to 2300 mAh g(-1) at 0.05 C (120 mA g(-1)) and 87% capacity retention (up to 630 mAh g(-1)) at 10 C after 152 cycles.
引用
收藏
页码:758 / 764
页数:7
相关论文
共 50 条
[21]   Battery materials for ultrafast charging and discharging [J].
Kang, Byoungwoo ;
Ceder, Gerbrand .
NATURE, 2009, 458 (7235) :190-193
[22]   Higher, Stronger, Better ... A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries [J].
Kraytsberg, Alexander ;
Ein-Eli, Yair .
ADVANCED ENERGY MATERIALS, 2012, 2 (08) :922-939
[23]   Silicon nanoparticles-graphene paper composites for Li ion battery anodes [J].
Lee, Jeong K. ;
Smith, Kurt B. ;
Hayner, Cary M. ;
Kung, Harold H. .
CHEMICAL COMMUNICATIONS, 2010, 46 (12) :2025-2027
[24]   Roles of nanosize in lithium reactive nanomaterials for lithium ion batteries [J].
Lee, Kyu Tae ;
Cho, Jaephil .
NANO TODAY, 2011, 6 (01) :28-41
[25]   A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes [J].
Liu, Nian ;
Wu, Hui ;
McDowell, Matthew T. ;
Yao, Yan ;
Wang, Chongmin ;
Cui, Yi .
NANO LETTERS, 2012, 12 (06) :3315-3321
[26]   Size-Dependent Fracture of Silicon Nanoparticles During Lithiation [J].
Liu, Xiao Hua ;
Zhong, Li ;
Huang, Shan ;
Mao, Scott X. ;
Zhu, Ting ;
Huang, Jian Yu .
ACS NANO, 2012, 6 (02) :1522-1531
[27]   Crumpled Graphene-Encapsulated Si Nanoparticles for Lithium Ion Battery Anodes [J].
Luo, Jiayan ;
Zhao, Xin ;
Wu, Jinsong ;
Jang, Hee Dong ;
Kung, Harold H. ;
Huang, Jiaxing .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (13) :1824-1829
[28]  
Magasinski A, 2010, NAT MATER, V9, P353, DOI [10.1038/NMAT2725, 10.1038/nmat2725]
[29]  
Mao S, 2012, ACS NANO, V6, P7505, DOI [10.1021/nn302818J, 10.1021/nn302818j]
[30]   A new reducing agent to prepare single-layer, high-quality reduced graphene oxide for device applications [J].
Mao, Shun ;
Yu, Kehan ;
Cui, Shumao ;
Bo, Zheng ;
Lu, Ganhua ;
Chen, Junhong .
NANOSCALE, 2011, 3 (07) :2849-2853