Mechanism of the low-energy fluxional process in [Fe-3(CO)(12-n)L-n] [n=0-2(3)]: A rebuttal

被引：22

作者：

Johnson, BFG

机构：

[1] University Chemical Laboratory, Cambridge CB2 IEW, Lensfield Road

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 09期

关键词：

D O I：

10.1039/a700227k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We respond to Mann's criticisms of the Ligand Polyhedral Model and its application to the fluxional behaviour of the compounds [Fe-3(CO)(12-n)L-n]. We reject his proposal that an analysis of a range of compounds by the Dunitz-Burgi method rules out the possibility of fluxionality by the libration of the Fe-3 triangle within the ligand icosahedron, and remind him that the librational mode corresponds to the first concerted bridge-opening bridge-closing mechanism.

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页码：1473 / 1479

页数：7

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