Inherently chiral derivatives of calix[5]crowns

被引：25

作者：

Arnecke, R

Bohmer, V

Ferguson, G

Pappalardo, S

机构：

[1] UNIV MAINZ,INST ORGAN CHEM,D-55099 MAINZ,GERMANY

[2] UNIV GUELPH,DEPT CHEM & BIOCHEM,GUELPH,ON N1G 2W1,CANADA

[3] UNIV CATANIA,DIPARTIMENTO SCI CHIM,I-95125 CATANIA,ITALY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 09期

关键词：

D O I：

10.1016/0040-4039(96)00048-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Complementary synthetic routes to the chiral (1,3)- and (1,2)-calix[5]crown ethers 2 and 3, respectively, are described. The regio- and stereochemical arrangement of the O-alkyl residues is deduced by NMR, and further supported by a single-crystal X-ray analysis of crown-5 derivative 3b.

引用

收藏

页码：1497 / 1500

页数：4

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