Synthesis and characterization of mixed iodide-naphthalene complexes of lanthanides

被引：13

作者：

Bochkarev, MN

Fedyushkin, IL

Larichev, RB

机构：

[1] G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603600 Niihnii Novgorod

来源：

RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 10期

关键词：

lanthanides; naphthalene; iodine; magnetic moment; stability;

D O I：

10.1007/BF01435400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The [LnI(2)(THF)(3)](2)(mu-C10H8) complexes were obtained by reactions of LnI(3)(THF)(3) (Ln = Ce, Pr, Nd, or Gd) with lithium and excess naphthalene. The magnetic moments of these complexes correspond to the oxidation state +3 of the metal atoms. The Yb-II complex, [YbI(DME)(2)](2)(mu-C10H8), was synthesized by the reaction of YbI2(DME)(2) with an equimolar amount of naphthalenelithium.

引用

页码：2443 / 2444

页数：2

共 5 条

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