Facile syntheses and structures of new metal-maleonitrilediselenolates [K([2.2.2]-cryptand)]3[Ag(Se2C2(CN)2)(Se6)], [K([2.2.2]-cryptand)]2[Ni(Se2C2(CN)2)2], and Ni(dppp)(Se2C2(CN)2)

被引：8

作者：

McLauchlan, CC ^{[1
]}

Ibers, JA ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 05期

关键词：

D O I：

10.1021/ic9901719

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Facile syntheses of [K([2.2.2]-cryptand)(3)Ag(Se2C2(CN)(2))(Se-6)] (1) and [K([2.2.2]-cryptand)](2)-[Ni(Se2C2(CN)(2))(2)] (2) are achieved through reaction of polyselenides with KNH2, [2.2.2]-cryptand, and AgBF4 or Ni(dppp)Cl-2 in acetonitrile. The syntheses of 2 and Ni(dppp)(Se2C2(CN)(2)) (3) may be achieved by reaction of 1 with NiCl2 or Ni(dppp)Cl-2 in dmf. These compounds represent the first easily prepared metal-maleonitrilediselenolate derivatives.

引用

页码：1046 / +

页数：4

共 19 条

[1] BEITRAGE ZUR CHEMIE DES SCHWEFELKOHLENSTOFFS UND SELENKOHLENSTOFFS .1. SALZE DER CYAN-DITHIOAMEISENSAURE [J].

BAHR, G ;

SCHLEITZER, G .

CHEMISCHE BERICHTE-RECUEIL, 1955, 88 (11) :1771-1777

[2] N-H ACTIVATION .1. OXIDATIVE ADDITION OF AMMONIA TO IRIDIUM(I) - ISOLATION, STRUCTURAL CHARACTERIZATION, AND REACTIVITY OF AMIDOIRIDIUM HYDRIDES [J].

CASALNUOVO, AL ;

CALABRESE, JC ;

MILSTEIN, D .

INORGANIC CHEMISTRY, 1987, 26 (07) :971-973

[3] THE CHEMISTRY AND SOLID-STATE PROPERTIES OF NICKEL, PALLADIUM AND PLATINUM BIS(MALEONITRILEDITHIOLATE) COMPOUNDS [J].

CLEMENSON, PI .

COORDINATION CHEMISTRY REVIEWS, 1990, 106 :171-203

[4] PREPARATION OF BIS(TRIFLUOROMETHYL,-1,2-DISELENETENE AND SOME 1,2-DISELENOLENE TRANSITION METAL COMPLEXES [J].

DAVISON, A ;

SHAWL, ET .

INORGANIC CHEMISTRY, 1970, 9 (08) :1820-&

[5]

Davison A., 1967, INORG SYNTH, V10, P8, DOI [DOI 10.1002/9780470132418.CH3, 10.1002/9780470132418.ch3]

[6] NEW DIMERIC GOLD SELENOLATES - PREPARATION AND CHARACTERIZATION OF [(NORMAL-C4H9)4N]2[AUSSEC=C(CN)2]2 AND [(NORMAL-C4H9)4N]2[AUSE2C=C(CN)2]2 [J].

DIETZSCH, W ;

FRANKE, A ;

HOYER, E ;

GRUSS, D ;

HUMMEL, HU ;

OTTO, P .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 611 (05) :81-84

[7]

Fourmigué M, 1998, ACTUAL CHIMIQUE, P9

[8] REACTIVE SELENOALDEHYDES FORMED FROM SELENENYL DERIVATIVES BY 1,2-ELIMINATION AND TRAPPED INSITU AS CYCLOADDUCTS WITH CONJUGATED DIENES [J].

KIRBY, GW ;

TRETHEWEY, AN .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (07) :1913-1922

[9] FACILE N-H CLEAVAGE OF AMMONIA [J].

KOELLIKER, R ;

MILSTEIN, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (06) :707-709

[10]

McCleverty J. A., 1968, PROG INORG CHEM, V10, P49, DOI DOI 10.1002/9780470166116.CH2

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