The invention of radical reactions .36. Synthetic studies related to 3-deoxy-D-manno-2-octulosonic acid (KDO)

被引：21

作者：

Barton, DHR

Jaszberenyi, JC

Liu, WS

Shinada, T

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1996年 / 52卷 / 08期

关键词：

D O I：

10.1016/0040-4020(95)01089-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An application of the Barton ester based radical reactions in carbohydrate chemistry is described. The chain-elongation reaction with ethyl alpha-trifluoroacetoxy acrylate 2, followed by treatment with phenylhydrazine provided 3-deoxy-alpha-hydrazono-octulosonates 8a,b, derivatives of KDO and its gluco-isomer in good yield.

引用

收藏

页码：2717 / 2726

页数：10

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