Supramolecular stereocontrol of octahedral metal-centered chirality. Ligand modulation

被引：44

作者：

Jodry, JJ ^{[1
]}

Frantz, R ^{[1
]}

Lacour, J ^{[1
]}

机构：

[1] Univ Geneva, Dept Chim Organ, CH-1211 Geneva, Switzerland

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 11期

关键词：

D O I：

10.1021/ic049661d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By associating chiral labile [FeL3](2+) complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L bpy, phen).

引用

页码：3329 / 3331

页数：3

共 31 条

[1]

Annunziata R, 2001, EUR J ORG CHEM, V2001, P173

[2] Supermolecules by design [J].

Caulder, DL ;

Raymond, KN .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :975-982

[3] Shuttles and muscles:: Linear molecular machines based on transition metals [J].

Collin, JP ;

Dietrich-Buchecker, C ;

Gaviña, P ;

Jimenez-Molero, MC ;

Sauvage, JP .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :477-487

[4] Molecular paneling via coordination [J].

Fujita, M ;

Umemoto, K ;

Yoshizawa, M ;

Fujita, N ;

Kusukawa, T ;

Biradha, K .

CHEMICAL COMMUNICATIONS, 2001, (06) :509-518

[5] A MACROMOLECULAR CONFORMATIONAL CHANGE DRIVEN BY A MINUTE CHIRAL SOLVATION ENERGY [J].

GREEN, MM ;

KHATRI, C ;

PETERSON, NC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) :4941-4942

[6] Quantitative formation of sandwich-shaped trinuclear silver(Ι) complexes and dynamic nature of their P⇆M flip motion in solution [J].

Hiraoka, S ;

Harano, K ;

Tanaka, T ;

Shiro, M ;

Shionoya, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) :5182-5185

[7] PFEIFFER EFFECT, OUTER-SPHERE COMPLEXATION, AND THE ABSOLUTE-CONFIGURATION OF DISSYMMETRIC COORDINATION-COMPOUNDS [J].

KIRSCHNER, S ;

AHMAD, N ;

MUNIR, C ;

POLLOCK, RJ .

PURE AND APPLIED CHEMISTRY, 1979, 51 (04) :913-923

[8]

Knof U, 1999, ANGEW CHEM INT EDIT, V38, P302, DOI 10.1002/(SICI)1521-3773(19990201)38:3<302::AID-ANIE302>3.0.CO

[9]

2-G

[10] Recent developments in chiral anion mediated asymmetric chemistry [J].

Lacour, J ;

Hebbe-Viton, V .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (06) :373-382

← 1 2 3 4 →