Quantitative formation of sandwich-shaped trinuclear silver(Ι) complexes and dynamic nature of their P⇆M flip motion in solution

被引：73

作者：

Hiraoka, S ^{[1
]}

Harano, K ^{[1
]}

Tanaka, T ^{[1
]}

Shiro, M ^{[1
]}

Shionoya, M ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 42期

关键词：

helical structures; N ligands; sandwich complexes; silver;

D O I：

10.1002/anie.200351068

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular flippers: The Ag3L2 complexes, which are quantitatively formed from two disk-shaped tridentate ligands (thiazolyl- or pyridyl-based) and three Ag+ ions, are helical and twist between the P and M forms (see scheme). The flip motion includes a relative 120° rotation between the two disk-shaped ligands connected by the Ag+ ions.

引用

收藏

页码：5182 / 5185

页数：4

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