Stereospecificity and mechanism in cation radical Diels-Alder and cyclobutanation reactions

被引:25
作者
Bauld, NL [1 ]
Yang, JK [1 ]
机构
[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
关键词
D O I
10.1021/ol9907567
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The cation radical Diels-Alder and cyclobutanation reactions of cis- and trans-1,2-(diaryloxy)ethenes with a cyclic and an acyclic diene have been found to be stereospecific, in accord with a concerted cycloaddition mechanism.
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页码:773 / 774
页数:2
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