Synthesis and characterisation of the chloride-bridged copper-ruthenium cluster dianion [{Ru6Cu2C(CO)(16)}(2)Cl-2](2-)

被引：22

作者：

Beswick, MA ^{[1
]}

Lewis, J ^{[1
]}

Raithby, PR ^{[1
]}

de Arellano, MCR ^{[1
]}

机构：

[1] DEPT CHEM, CAMBRIDGE CB2 1EW, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 21期

关键词：

D O I：

10.1039/dt9960004033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed-metal ruthenium-copper cluster dianion [{Ru6Cu2C(CO)(16)}Cl-2(2)](2-) 1 has been synthesised in quantitative yield from [Ru6C(CO)(16)](2-) and CuCl; the crystal structure of the [N(PPh(3))(2)](+) salt shows that the two Ru-6 octahedra are linked by a rectangular planar arrangement of copper atoms two opposite edges of which are bridged by chlorine atoms.

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页码：4033 / 4034

页数：2

相关论文

共 16 条

[1] EFFECT OF THE PHOSPHINE LIGAND CONE ANGLE ON THE METAL FRAMEWORKS OF HETERONUCLEAR CLUSTER COMPOUNDS CONTAINING CU(PR3) (R = ALKYL OR ARYL) GROUPS - X-RAY STRUCTURE ANALYSES OF [CU2RU4(MU-3-H)2(CO)12(PR3)2] (R = CYCLO-C6H11 OR CHME2) [J].

ADATIA, T ;

MCCARTHY, PJ ;

MCPARTLIN, M ;

RIZZA, M ;

SALTER, ID .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (16) :1106-1108

[2] STRUCTURE OF OCTADECACARBONYL-1,2,3-4,5,6-BIS-MU-3-[(ETA-TOLUENE)CUPRIO]-OCTAHEDRO-HEXARUTHENIUM, (C6H5CH3)2CU2RU6(CO)18 [J].

ANSELL, GB ;

MODRICK, MA ;

BRADLEY, JS .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (MAR) :365-368

[3]

BAILEY PJ, 1993, J ORGANOMET CHEM, V293, P459

[4]

BESWICK MA, UNPUB ANGEW CHEM INT

[5] SYNTHESIS AND MOLECULAR-STRUCTURE OF BIS(ACETONITRILECUPRIO)CARBIDOHEXADECACARBONYLHEXAURTHENIUM, [(CH3CN)2CU2RU6C(CO)16], A BIMETALLIC CARBIDOCARBONYL CLUSTER CONTAINING A COPPER-COPPER BOND [J].

BRADLEY, JS ;

PRUETT, RL ;

HILL, E ;

ANSELL, GB ;

LEONOWICZ, ME ;

MODRICK, MA .

ORGANOMETALLICS, 1982, 1 (05) :748-752

[6]

DIEBOLD MP, 1990, POLYHEDRON, V9, P175

[7] BORIDE CLUSTER FUSION VIA AN M4-UNIT (M = CU OR AG) - MOLECULAR-STRUCTURE OF [PPN][[-RU4H(CO)12B-]2CU4(MU-CL)][CL] [PPN = (PPH3)2N] [J].

DRAPER, SM ;

HATTERSLEY, AD ;

HOUSECROFT, CE ;

RHEINGOLD, AL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (18) :1365-1367

[8]

Farrugia L. J., 1990, ADV ORGANOMET CHEM, V31, P301

[9] H2RU6(CO)18, [HRU6(CO)18]-, AND [RU6(CO)18]2- - SIMPLE HIGH-YIELD ROUTE TO THESE CLUSTERS AND THE X-RAY STRUCTURE OF [PH3MEP]2 [RU6(CO)18] [J].

JACKSON, PF ;

JOHNSON, BFG ;

LEWIS, J ;

MCPARTLIN, M ;

NELSON, WJH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (17) :735-736

[10] SYNTHESIS OF MIXED-METAL CLUSTERS BY THE REACTION OF THE UNSATURATED CLUSTER [OS3(MU-H)2(CO)10] WITH TRANSITION-METAL HYDRIDES - THE X-RAY CRYSTAL-STRUCTURES OF [OS3H3(CO)10(CU(PPH3))] AND [OS3H3(CO)11-(IR(PPH3))] [J].

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR ;

AZMAN, SN ;

SYEDMUSTAFFA, B ;

TAYLOR, MJ ;

WHITMIRE, KH ;

CLEGG, W .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (10) :2111-2118