Preparation and Crystal Growth of Na24Si136

被引：88

作者：

Beekman, Matt ^{[1
]}

Baitinger, Michael ^{[2
]}

Borrmann, Horst ^{[2
]}

Schnelle, Walter ^{[2
]}

Meier, Katrin ^{[2
]}

Nolas, George S. ^{[1
]}

Grin, Yuri ^{[2
]}

机构：

[1] Univ S Florida, Dept Phys, Tampa, FL 33620 USA

[2] Max Planck Inst Chem Phys Fester Stoffe, Dresden, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 28期

关键词：

SILICON; CONSOLIDATION; OXIDATION; PRESSURE; NASI;

D O I：

10.1021/ja903362b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) The synthesis and single crystal growth of clathrate-II Na24Si136 is performed in one step applying the spark plasma treatment to the precursor Na4Si4. The reported results demonstrate a new route to intermetallic compounds facilitated by the electric field and current. SPS is revealed to offer significant opportunities as a novel preparatory method for synthesis and crystal growth of solid state materials. © 2009 American Chemical Society.

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页码：9642 / 9643

页数：2

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