Redox-active organometallic vesicles: Aqueous self-assembly of a diblock copolymer with a hydrophilic polyferrocenylsilane polyelectrolyte block

被引：104

作者：

Power-Billard, KN

Spontak, RJ ^{[1
]}

Manners, I

机构：

[1] N Carolina State Univ, Dept Chem Engn, Raleigh, NC 27695 USA

[2] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA

[3] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期

关键词：

block copolymers; liposomes; nanostructures; ring-opening polymerization; self-assembly;

D O I：

10.1002/anie.200352819

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A water-soluble poly(dimethylsiloxane-b-ferrocenylsilane) diblock copolymer containing a hydrophilic cationic polyferrocene block, which is formed in a self-assembly process, yields redox-active vesicles with a diameter of approximately 85 nm (see figure) in which the organometallic block is located on both the outside and the inside of the formed aggregates.

引用

页码：1260 / 1264

页数：5

共 70 条

[1] Solvent-regulated ordering in block copolymers [J].