Synthesis of [(η5-C5H5)Fe(CO)2BCl2•NC5H4-4-Me] from [(η5-C5H5)Fe(CO)2BCl2]:: First preparation of a Lewis acid-base adduct from a boryl complex

被引:42
作者
Braunschweig, H [1 ]
Radacki, K [1 ]
Seeler, F [1 ]
Whittell, GR [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
关键词
D O I
10.1021/om049555j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The (dichloroboryl)iron complex [(eta(5)-C5H5)-Fe(CO)(2)BCl2] and its corresponding Lewis base adduct with 4-methylpyridine have been prepared; characterization by single-crystal X-ray diffraction has afforded a structural comparison between the two species.
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页码:4178 / 4180
页数:3
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