Synthesis and characterization of colloidal β-HgS quantum dots

High-quality colloidal mercury sulfide quantum dots (QDs) are synthesized at room temperature using a strategy combining the effects of strongly binding Hg(II) ligands and metal/chalcogen precursor phase separation. This combination prevents both the rapid precipitation of bulk HgS in preparations involving only weak Hg(II) ligands and the reduction of mercury that takes place when only strongly binding ligands are used to slow the growth kinetics. Both the linear absorption and complementary band edge emission of the synthesized HgS QDs exhibit narrow, size-dependent transitions between 500 and 800 rim for sizes ranging from 1 to 5 nm in diameter. The metastable zinc blende phase of HgS is verified by wide-angle X-ray diffraction experiments and suggests potentially large tunable band edges if larger HgS nanocrystals that approach the bulk (zero energy) gap can be made. Growth of HgS QDs can be arrested by subsequent addition of Cd or Zn to the surface, after which the QDs can be stabilized with long-chain thiols or amines.