Effect of LiO2 and PbO additions on abnormal grain growth in the Pb(Mg1/3Nb2/3)O3-35 mol% PbTiO3 system

被引:42
作者
Fisher, JG
Kim, MS
Lee, HY
Kang, SJL [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Sun Moon Univ, Div Mat & Chem Engn, Asan 336708, South Korea
关键词
D O I
10.1111/j.1551-2916.2004.00937.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Abnormal grain growth in Pb(Mg1/3Nb2/3)O-3-35 mol% PbTiO3 (PMN-35PT) ceramics doped with Li2O and PbO has been investigated. Replacing the PbO dopant with up to 2 mol% Li2O caused an increase in the number of abnormal grains. For the composition containing 2 mol% Li2O and 6 mol% PbO, the amount of abnormal grain growth decreased with increasing sintering temperature. Single crystals of similar to6 mm x 6 mm x 2 mm thickness were grown from the 2 mol% Li2O, 6 mol% PbO-containing composition via the templated grain growth method. Grain growth behavior with temperature is explained in terms of the effect of Li2O on interface-reaction-controlled grain growth and the critical driving force.
引用
收藏
页码:937 / 942
页数:6
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