Importance of dewetting in organic molecular-beam deposition:: Pentacene on gold

被引:88
作者
Beernink, G [1 ]
Strunskus, T [1 ]
Witte, G [1 ]
Wöll, C [1 ]
机构
[1] Ruhr Univ Bochum, Lehrstuhl Phys Chem 1, D-44780 Bochum, Germany
关键词
D O I
10.1063/1.1775040
中图分类号
O59 [应用物理学];
学科分类号
摘要
Organic molecular-beam deposition of pentacene on gold substrates has been investigated using a multitechnique approach. The morphology of the organic thin films depends strongly on the substrate temperature. Pronounced dewetting and island formation are observed at room temperature. Whereas pentacene molecules adopt a planar monolayer structure, they continue to grow in an upright orientation in multilayer films as inferred from x-ray absorption spectroscopy and atomic force microscopy. These results are in pronounced contrast to a recent scanning tunneling microscopy (STM) study by Kang and Zhu [Appl. Phys. Lett. 82, 3248 (2003)] and indicate fundamental problems in the interpretation of STM measurements for organic thin films. (C) 2004 American Institute of Physics.
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页码:398 / 400
页数:3
相关论文
共 18 条
[1]  
Alvarado SF, 2002, ADV FUNCT MATER, V12, P117, DOI 10.1002/1616-3028(20020201)12:2<117::AID-ADFM117>3.0.CO
[2]  
2-6
[3]   Functionalized pentacene: Improved electronic properties from control of solid-state order [J].
Anthony, JE ;
Brooks, JS ;
Eaton, DL ;
Parkin, SR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (38) :9482-9483
[4]   Hyperthermal molecular beam deposition of highly ordered organic thin films [J].
Casalis, L ;
Danisman, MF ;
Nickel, B ;
Bracco, G ;
Toccoli, T ;
Iannotta, S ;
Scoles, G .
PHYSICAL REVIEW LETTERS, 2003, 90 (20) :4
[5]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[6]  
2-9
[7]   Pentacene organic thin-film transistors - Molecular ordering and mobility [J].
Gundlach, DJ ;
Lin, YY ;
Jackson, TN ;
Nelson, SF ;
Schlom, DG .
IEEE ELECTRON DEVICE LETTERS, 1997, 18 (03) :87-89
[8]   Pi-stacked pentacene thin films grown on Au(111) [J].
Kang, JH ;
Zhu, XY .
APPLIED PHYSICS LETTERS, 2003, 82 (19) :3248-3250
[9]   Charge carrier transport in organic semiconductors [J].
Karl, N .
SYNTHETIC METALS, 2003, 133 :649-657
[10]   Epitaxial growth of pentacene films on metal surfaces [J].
Lukas, S ;
Söhnchen, S ;
Witte, G ;
Wöll, C .
CHEMPHYSCHEM, 2004, 5 (02) :266-270