Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

被引：55

作者：

Mochizuki, D

Shimojima, A

Kuroda, K ^{[1
]}

机构：

[1] Waseda Univ, Dept Appl Chem, Shinjuku Ku, Tokyo 1698555, Japan

[2] Waseda Univ, Mat Sci & Technol Lab, Shinjuku Ku, Tokyo 1690051, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 41期

关键词：

D O I：

10.1021/ja027512t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route. Copyright © 2002 American Chemical Society.

引用

页码：12082 / 12083

页数：2

共 16 条

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Barrer RM., 1982, HYDROTHERMAL CHEM ZE

[2] FORMATION OF INTERCALATION COMPOUNDS OF A LAYERED SODIUM OCTOSILICATE WITH N-ALKYLTRIMETHYLAMMONIUM IONS AND THE APPLICATION TO ORGANIC DERIVATIZATION [J].