共 53 条
Novel 3D coordination palladium-network complex: A recyclable catalyst for Suzuki-Miyaura reaction
被引:77
作者:
Yamada, Yoichi M. A.
[1
]
Maeda, Yasunari
[1
]
Uozumi, Yasuhiro
[1
]
机构:
[1] Inst Mol Sci, Okazaki, Aichi 4448787, Japan
关键词:
D O I:
10.1021/ol0615026
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A novel solid-phase 3D metal-organic coordination network catalyst was prepared via self-assembly from PdCl2(CH3CN)(2) and a trisphosphine hub with three flexible alkyl-chain linkers. This insoluble network complex efficiently catalyzed the Suzuki-Miyaura reaction under atmospheric conditions in water. This catalyst was reused without loss of catalytic activity.
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页码:4259 / 4262
页数:4
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