Gas phase atmospheric bromine photochemistry

This paper reviews the current knowledge of gas phase bromine photochemistry and presents a budget study of atmospheric bromine species. The effectiveness of the ozone catalytic loss cycles involving bromine is quantified by considering their chain length and effectiveness. The chain effectiveness is a new variable defined as the chain length multiplied by the rate of the cycle's rate-limiting step. The chain effectiveness enables a fair comparison of different catalytic cycles involving species which have very different concentrations. This analysis clearly shows that below 25 km the BrO/ClO and BrO/HO2 cycles are among the most important ozone destruction cycles.