Recent aspects of asymmetric catalysis by immobilized chiral metal catalysts

被引:83
作者
Bianchini, C [1 ]
Barbaro, P [1 ]
机构
[1] CNR, Ist Studio Stereochim & Energet Composti Coor, I-50132 Florence, Italy
关键词
asymmetric catalysis; heterogeneous catalysis; immobilization; catalyst recycling;
D O I
10.1023/A:1013825114636
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this paper, we have reviewed recent achievements in the field of asymmetric catalysis by metal complexes immobilized onto inorganic and organic supports. Besides allowing for facile catalyst recovery and reuse, immobilized metal complexes show a number of diverse applications and unique performances.
引用
收藏
页码:17 / 32
页数:16
相关论文
共 69 条
[1]   Best design of heterogenized β-aminoalcohols for improvement of enantioselective addition of diethylzinc to benzaldehyde [J].
Abramson, S ;
Laspéras, M ;
Galarneau, A ;
Desplantier-Giscard, D ;
Brunel, D .
CHEMICAL COMMUNICATIONS, 2000, (18) :1773-1774
[2]   Polymer-supported chiral Co(salen) complexes: Synthetic applications and mechanistic investigations in the hydrolytic kinetic resolution of terminal epoxides [J].
Annis, DA ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) :4147-4154
[3]   Immobilization of heterobimetallic multifunctional asymmetric catalyst [J].
Arai, T ;
Hu, QS ;
Zheng, XF ;
Pu, L ;
Sasai, H .
ORGANIC LETTERS, 2000, 2 (26) :4261-4263
[4]   A new multifunctional heterobimetallic asymmetric catalyst for Michael additions and tandem Michael-Aldol reactions [J].
Arai, T ;
Sasai, H ;
Aoe, K ;
Okamura, K ;
Date, T ;
Shibasaki, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (01) :104-106
[5]   A new technique for anchoring homogeneous catalysts [J].
Augustine, R ;
Tanielyan, S ;
Anderson, S ;
Yang, H .
CHEMICAL COMMUNICATIONS, 1999, (13) :1257-1258
[6]  
Bae SJ, 2000, CHEM COMMUN, P31
[7]   Synthesis and evaluation of a chiral heterogeneous transfer hydrogenation catalyst [J].
Bayston, DJ ;
Travers, CB ;
Polywka, MEC .
TETRAHEDRON-ASYMMETRY, 1998, 9 (12) :2015-2018
[8]   Preparation and use of a polymer supported BINAP hydrogenation catalyst [J].
Bayston, DJ ;
Fraser, JL ;
Ashton, MR ;
Baxter, AD ;
Polywka, MEC ;
Moses, E .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (09) :3137-3140
[9]   Asymmetric catalysis on solids [J].
Bein, T .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1999, 4 (01) :85-96
[10]   Hydrogenation of α-acetamidocinnamic acid with polystyrene-supported rhodium catalysts [J].
Bhaduri, S ;
Lahiri, GK ;
Munshi, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 606 (02) :151-155