Chemical states and electrical properties of a high-k metal oxide/silicon interface with oxygen-gettering titanium-metal-overlayer

被引:37
作者
Seo, Kang-Ill [1 ]
Lee, Dong-Ick
Pianetta, Piero
Kim, Hyoungsub
Saraswat, Krishna C.
McIntyre, Paul C.
机构
[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[2] Stanford Synchrotron Radiat Lab, Stanford, CA 94305 USA
[3] Sungkyunkwan Univ, Sch Adv Mat Sci & Engn, Suwon 440746, South Korea
[4] Stanford Univ, Dept Elect Engn, Stanford, CA 94305 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2358834
中图分类号
O59 [应用物理学];
学科分类号
摘要
The authors report on the chemical bonding structure of the HfO2/Si (001) stack after the SiO2 interfacial layer (IL) is partially removed by a reactive titanium metal overlayer. Using synchrotron photoelectron spectroscopy, they found that ultrathin SiO2-like IL similar to 6.5 angstrom thick, which is significantly less than the initial SiO2 IL thickness of similar to 15 angstrom, exists at the HfO2/Si interface with an overlying Ti electrode. The dissociated Si from SiO2 IL is believed to go onto Si substrate where it regrows epitaxially. The interfacial trap density of the Ti-electrode sample was extracted to be similar to 1.6 x 10(11) eV(-1) cm(-2) near the midgap of Si, which was comparable to that of the control sample with W electrode. (c) 2006 American Institute of Physics.
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页数:3
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