Catalytic imino-Diels-Alder reactions of 2-aminodienes:: a simple entry into structurally diverse pipecolic acid derivatives

被引：14

作者：

Barluenga, J ^{[1
]}

Fernández, MA ^{[1
]}

Aznar, F ^{[1
]}

Valdés, C ^{[1
]}

机构：

[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, E-33071 Oviedo, Spain

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(02)01892-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereoselective synthesis of 4-aminotetrahydropyridines by cycloaddition reaction of 2-amino-1,3-butadienes with N-alkyl and N-aryliminoesters in the presence of a catalytic amount of a Lewis acid is described. The reaction proceeds with differently substituted 2-aminodienes, giving rise to structurally diverse pipecolic acid derivatives. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：8159 / 8163

页数：5

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