A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs

被引：173

作者：

Bhola, Radha ^{[1
]}

Payamyar, Payam ^{[2
]}

Murray, Daniel J. ^{[1
]}

Kumar, Bharat ^{[1
]}

Teator, Aaron J. ^{[1
]}

Schmidt, Martin U. ^{[3
]}

Hammer, Sonja M. ^{[3
]}

Saha, Animesh ^{[2
]}

Sakamoto, Junji ^{[2
]}

Schlueter, A. Dieter ^{[2
]}

King, Benjamin T. ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA

[2] ETH, Inst Polymers, Polymer Chem Lab, Dept Mat, CH-8093 Zurich, Switzerland

[3] Goethe Univ Frankfurt, Inst Inorgan & Analyt Chem, D-60438 Frankfurt, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 38期

基金：

美国国家科学基金会;

关键词：

COVALENT ORGANIC FRAMEWORK; SOLID-STATE; MOLECULAR-CRYSTALS; GRAPHENE; 2D; EXFOLIATION; PHOTODIMERIZATION; DELAMINATION; NANOSHEETS; CHEMISTRY;

D O I：

10.1021/ja404351p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A two-dimensional polymer (2DP) based on the dimerization of anthraceno groups arranged in a triptycene motif is reported. A photoinduced polymerization is performed in the crystalline state and gives a lamellar 2DP via a crystal-to-crystal (but not single-crystal to single-crystal) transformation. Solvent-induced exfoliation provides monolayer sheets of the 2DP. The 2DP is considered to be a tiling, a mathematical approach that facilitates structural elucidation.

引用

页码：14134 / 14141

页数：8

共 47 条

[41]

SCHMIDT G M J, 1971, Pure and Applied Chemistry, V27, P647

[42] INFRARED SPECTRA OF PHOTODIMERS OF ANTHRACENE BENZO[A)ANTHRACENE AND TETRACENT [J].