Polymorphism of ((tosylimino)iodo)-o-toluene: Two new modes of polymeric association for ArINTs

被引：14

作者：

Cicero, RL ^{[1
]}

Zhao, D ^{[1
]}

Protasiewicz, JD ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT CHEM,CLEVELAND,OH 44106

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 02期

关键词：

D O I：

10.1021/ic951031b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two different polymorphic structures of (tosyliminoiodo)-o-toluene, o-TolylINTs, (1) have been determined. The structure of polymorph A (triclinic form) reveals a unique infinite ladder type polymer created by parallel single chain polymers of 1 (associated through I ... O linkages) bridged by weak I ... N interchain associations. The structure of polymorph B (monoclinic form) forms a polymer built of a backbone containing I ... O linkages, similar to half of the ladder structure of polymorph A. These two structures represent intermediate polymeric forms of the two extremes observed for PhINTs and MeslNTs.

引用

页码：275 / &

页数：3

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