Molecular orientation of CuPc thin films on C60/Ag(111)

被引:99
作者
Huang, Han [1 ]
Chen, Wei [1 ,2 ]
Chen, Shi [1 ]
Qi, Dong Chen [1 ]
Gao, Xing Yu [1 ]
Wee, Andrew Thye Shen [1 ]
机构
[1] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
[2] Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
关键词
copper compounds; fullerenes; molecular orientation; monolayers; organic semiconductors; scanning tunnelling microscopy; semiconductor thin films; XANES; SCANNING-TUNNELING-MICROSCOPY; COPPER PHTHALOCYANINE; SOLAR-CELLS; PHOTOVOLTAIC CELL; IMAGE-CONTRAST; EPITAXY; GRAPHITE; AU(111); AG(111); GROWTH;
D O I
10.1063/1.3122940
中图分类号
O59 [应用物理学];
学科分类号
摘要
The molecular orientation of copper(II) phthalocyanine (CuPc) thin films on monolayer C-60 on Ag(111) was studied by in situ near-edge x-ray absorption fine structure measurements and low-temperature scanning tunneling microscopy. It is found that in densely packed thin films, CuPc molecules adopt a standing-up configuration with the molecular pi-plane tilting slightly from the surface normal on monolayer C-60.
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页数:3
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