The Thermoelectric Performance of Poly(3,4-ethylenedi oxythiophene)/Poly(4-styrenesulfonate) Thin Films

被引:109
作者
Chang, Kuei-Chien [1 ]
Jeng, Ming-Shan [1 ]
Yang, Chang-Chung [1 ]
Chou, Ya-Wen [1 ]
Wu, Shih-Kuo [1 ]
Thomas, Marin Andrew [1 ]
Peng, Yen-Chun [1 ]
机构
[1] Ind Technol Res Inst, Energy & Environm Res Labs, Hsinchu 310, Taiwan
关键词
PEDOT-PSS; conductive polymer; thermoelectrical; Seebeck coefficient; power factor; ELECTRICAL-CONDUCTIVITY; PEDOT/PSS; ENHANCEMENT; TRANSPORT; MECHANISM; SEEBECK;
D O I
10.1007/s11664-009-0821-4
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The thermoelectric performance of synthetic conductive polymers, poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) (PEDOT/PSS), is explored. The effects of the dielectric solvent, dimethyl sulfoxide (DMSO), and of the ratio of PEDOT to PSS in the polymeric PEDOT/PSS thin films were studied systematically. Within the parameter range studied in this work, the variation of electrical conductivity overwhelmed the variation of the Seebeck coefficient, and the optimal power factor is basically determined by the highest electrical conductivity, because the Seebeck coefficient remains small over a wide range of DMSO concentrations and PEDOT:PSS ratios.
引用
收藏
页码:1182 / 1188
页数:7
相关论文
共 33 条
[1]  
Bohm W, 1997, PHYS STATUS SOLIDI A, V160, P81, DOI 10.1002/1521-396X(199703)160:1<81::AID-PSSA81>3.0.CO
[2]  
2-S
[3]   POLARONS, BIPOLARONS, AND SOLITONS IN CONDUCTING POLYMERS [J].
BREDAS, JL ;
STREET, GB .
ACCOUNTS OF CHEMICAL RESEARCH, 1985, 18 (10) :309-315
[4]  
Chen G., 2005, PAPPAL SER MECH ENG
[5]   The origin of the high conductivity of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS) plastic electrodes [J].
Crispin, X. ;
Jakobsson, F. L. E. ;
Crispin, A. ;
Grim, P. C. M. ;
Andersson, P. ;
Volodin, A. ;
van Haesendonck, C. ;
Van der Auweraer, M. ;
Salaneck, W. R. ;
Berggren, M. .
CHEMISTRY OF MATERIALS, 2006, 18 (18) :4354-4360
[6]   Optical study and vibrational analysis of the poly(3,4-ethylenedioxythiophene) (PEDT) [J].
Garreau, S ;
Louarn, G ;
Lefrant, S ;
Buisson, JP ;
Froyer, G .
SYNTHETIC METALS, 1999, 101 (1-3) :312-313
[7]   Nano-structured conducting polymer network based on PEDOT-PSS [J].
Ghosh, S ;
Inganäs, O .
SYNTHETIC METALS, 2001, 121 (1-3) :1321-1322
[8]   Characterization of the PEDOT-PSS system by means of X-ray and ultraviolet photoelectron spectroscopy [J].
Greczynski, G ;
Kugler, T ;
Salaneck, WR .
THIN SOLID FILMS, 1999, 354 (1-2) :129-135
[9]  
Groenendaal BL, 2000, ADV MATER, V12, P481, DOI 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO
[10]  
2-C