Metallic conductivity in a polyoxovanadate radical salt of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF):: Synthesis, structure, and physical characterization of β"-(BEDT-TTF)5[H3V10O28]•4H2O

被引：93

作者：

Coronado, E

Galán-Mascarós, JR

Giménez-Saiz, C

Gómez-García, CJ

Martínez-Ferrero, E

Almeida, M

Lopes, EB

机构：

[1] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain

[2] Inst Tecnol & Nucl, P-2686 Sacavem, Portugal

来源：

ADVANCED MATERIALS | 2004年 / 16卷 / 04期

关键词：

D O I：

10.1002/adma.200304773

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first hybrid radical salt of U bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) using a polyoxovanadate as the counterion, (BEDT-TTF)(5)[H3V10O28](.)4H(2)O, has been obtained and characterized. It contains segregated mixed-valence 2D stacks of organic radicals interleaved by anionic layers of [H3V10O28](3-) anions (see Figure). This compound exhibits high electrical conductivity at room temperature and metallic behavior down to low temperatures.

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页码：324 / +

页数：5

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