First report of reversible addition-fragmentation chain transfer (RAFT) polymerisation in room temperature ionic liquids

被引：125

作者：

Perrier, S

Davis, TP ^{[1
]}

Carmichael, AJ

Haddleton, DM

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 19期

关键词：

D O I：

10.1039/b206534g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Reversible Addition-Fragmentation chain Transfer (RAFT) polymerisation of acrylates, methacrylates and styrene is reported for the first time in room temperature ionic liquids; the acrylate and methacrylate polymerisations show a living character and lead to well-characterised polymers, with narrow polydispersity ( < 1.3); in the case of styrene, the insolubility of the polymer in the ionic liquids stops the polymerisation at an early stage.

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收藏

页码：2226 / 2227

页数：2

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