Electrochemically driven clathration/declathration of ferrocene and its derivatives by a nanometer-sized coordination cage

被引：111

作者：

Sun, WY

Kusukawa, T

Fujita, M

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Sci & Technol Corp, CREST, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 39期

关键词：

D O I：

10.1021/ja0206285

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical, NMR, and crystallographic studies clearly indicate that the clathration and declathration of ferrocene and its derivatives in a self-assmbled Pd(II)-linked nanometer-sized cage can be controlled by the oxidation state of the guest. Namely, the guests are clathrated when they are reduced but declathrated when they are oxidized. The process is rapid on the NMR time scale but slow on the CV time scale. Copyright © 2002 American Chemical Society.

引用

页码：11570 / 11571

页数：2