Pincer-porphyrin hybrids

被引:29
作者
Suijkerbuijk, BMJM
Lutz, M
Spek, AL
van Koten, G
Gebbink, RJMK
机构
[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
[2] Univ Utrecht, Bijvoet Ctr Biomol Res, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1021/ol049034s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Starting from tetrakis(3,5-bis(bromomethyl)phenyl)porphyrin, pincer-porphyrin hybrid molecules (tetrakis(ECE-pincer)porphyrin; E = N, P, S) based on a tetraphenylporphyrin skeleton have been prepared in high yields. These multi-ligand site compounds could be selectively metalated at their peripheries, which was shown by X-ray crystallography.
引用
收藏
页码:3023 / 3026
页数:4
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