Catalytic Strategies for Changing the Energy Content and Achieving C-C Coupling in Biomass-Derived Oxygenated Hydrocarbons

被引:78
作者
Simonetti, Dante A. [1 ]
Dumesic, James A. [1 ]
机构
[1] Univ Wisconsin, Dept Biol & Chem Engn, Madison, WI 53706 USA
基金
美国国家科学基金会;
关键词
biomass; catalysis; renewable resources; sustainable energy;
D O I
10.1002/cssc.200800105
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This Concept examines the opportunities for the use of biomass feedstocks in the production of liquid fuels for the transportation sector of society. The cost-competitive conversion of biomass into liquid fuels involves the integration of processes that operate on lignocellulosic feeds with processes that convert specific fractions of lignocellulose. A brief description of current energy systems is given to indicate the potential contributions of biomass to replace fossil fuel feedstocks for energy production, followed by a description of current biomass-conversion technologies. Specific focus is given to promising reaction pathways and novel research opportunities for conversion of the carbohydrate fraction of lignocellulose into fuels with targeted structures.
引用
收藏
页码:725 / 733
页数:9
相关论文
共 63 条
[1]  
[Anonymous], 2007, BP STAT REV WORLD EN
[2]  
[Anonymous], 2007, Key world energy statistics
[3]   Biomass gasification to hydrogen and syngas at low temperature: Novel catalytic system using fluidized-bed reactor [J].
Asadullah, M ;
Ito, S ;
Kunimori, K ;
Yamada, M ;
Tomishige, K .
JOURNAL OF CATALYSIS, 2002, 208 (02) :255-259
[4]   Single-reactor process for sequential aldol-condensation and hydrogenation of biomass-derived compounds in water [J].
Barrett, C. J. ;
Chheda, J. N. ;
Huber, G. W. ;
Dumesic, J. A. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 66 (1-2) :111-118
[5]  
Bass J. D., 2003, ANGEW CHEM, V115, P5377, DOI DOI 10.1002/ANGE.200352181
[6]   Acid-base bifunctional and dielectric outer-sphere effects in heterogeneous catalysis: A comparative investigation of model primary amine catalysts [J].
Bass, JD ;
Solovyov, A ;
Pascall, AJ ;
Katz, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) :3737-3747
[7]   The effect of outer-sphere acidity on chemical reactivity in a synthetic heterogeneous base catalyst [J].
Bass, JD ;
Anderson, SL ;
Katz, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) :5219-5222
[8]  
Boyle G., 2012, Renewable Energy: Power for a Sustainable Future
[9]   CATALYSIS IN THERMAL BIOMASS CONVERSION [J].
BRIDGWATER, AV .
APPLIED CATALYSIS A-GENERAL, 1994, 116 (1-2) :5-47
[10]   CONVERSION OF METHANOL AND OTHER O-COMPOUNDS TO HYDROCARBONS OVER ZEOLITE CATALYSTS [J].
CHANG, CD ;
SILVESTRI, AJ .
JOURNAL OF CATALYSIS, 1977, 47 (02) :249-259