Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte

被引:656
作者
Lu, Qingwen [1 ]
He, Yan-Bing [1 ]
Yu, Qipeng [1 ]
Li, Baohua [1 ]
Kaneti, Yusuf Valentino [1 ]
Yao, Youwei [1 ]
Kang, Feiyu [1 ,2 ]
Yang, Quan-Hong [1 ,2 ,3 ]
机构
[1] Tsinghua Univ, Grad Sch Shenzhen, Engn Lab Functionalized Carbon Mat & Engn, Lab Next Generat Power & Energy Storage Batteries, Shenzhen 518055, Peoples R China
[2] Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen 518055, Peoples R China
[3] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
ION BATTERIES; RECHARGEABLE BATTERIES; SECONDARY BATTERIES; HYBRID ELECTROLYTES; SOLID-ELECTROLYTE; ANODES; DEPOSITION; SEPARATOR; LIQUID; GROWTH;
D O I
10.1002/adma.201604460
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A 3D network gel polymer electrolyte (3D-GPE) is designed for lithium metal batteries and prepared by an initiator-free one-pot ring-opening polymerization technique. This 3D-GPE exhibits an unprecedented combination of mechanical strength, ionic conductivity, and more importantly, effective suppression of Li dendrite growth. The produced lithium-based battery presents long life, high rate, and excellent safety.
引用
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页数:8
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