Synthesis of star-shaped poly(ε-caprolactone) via 'click' chemistry and 'supramolecular click' chemistry

被引:144
作者
Hoogenboom, Richard [1 ]
Moore, Brian C. [1 ]
Schubert, Ulrich S. [1 ]
机构
[1] Eindhoven Univ Technol, Ctr NanoSci, LMU Munchen, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1039/b608313g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of star-shaped poly(epsilon-caprolactone) is described via azide-alkyne cycloaddition ('click' chemistry) and via self-assembly of polymeric ligands into [2 x 2] grid-like metal complexes ('supramolecular click' chemistry).
引用
收藏
页码:4010 / 4012
页数:3
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共 30 条
[1]   Metal/ligand-induced formation of metallo-supramolecular polymers [J].
Beck, JB ;
Ineman, JM ;
Rowan, SJ .
MACROMOLECULES, 2005, 38 (12) :5060-5068
[2]   Synthesis of readily modifiable cyclodextrin analogues via cyclodimerization of an alkynyl-azido trisaccharide [J].
Bodine, KD ;
Gin, DY ;
Gin, MS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (06) :1638-1639
[3]   Supramolecular polymers [J].
Brunsveld, L ;
Folmer, BJB ;
Meijer, EW ;
Sijbesma, RP .
CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097
[4]   Click chemistry as a powerful tool for the construction of functional poly(p-phenyleneethynylene)s:: Comparison of pre- and postfunctionalization schemes [J].
Englert, BC ;
Bakbak, S ;
Bunz, UHF .
MACROMOLECULES, 2005, 38 (14) :5868-5877
[5]   Gradient polymer elution chromatographic analysis of α,ω-dihydroxypolystyrene synthesized via ATRP and click chemistry [J].
Gao, HF ;
Louche, G ;
Sumerlin, BS ;
Jahed, N ;
Golas, P ;
Matyjaszewski, K .
MACROMOLECULES, 2005, 38 (22) :8979-8982
[6]   Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host [J].
Hahn, U ;
Elhabiri, M ;
Trabolsi, A ;
Herschbach, H ;
Leize, E ;
Van Dorsselaer, A ;
Albrecht-Gary, AM ;
Nierengarten, JF .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (33) :5338-5341
[7]   Dendronized linear polymers via "click chemistry" [J].
Helms, B ;
Mynar, JL ;
Hawker, CJ ;
Fréchet, JMJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (46) :15020-15021
[8]   Combination of orthogonal supramolecular interactions in polymeric architectures [J].
Hofmeier, H ;
Schubert, US .
CHEMICAL COMMUNICATIONS, 2005, (19) :2423-2432
[9]   High molecular weight supramolecular polymers containing both terpyridine metal complexes and ureidopyrimidinone quadruple hydrogen-bonding units in the main chain [J].
Hofmeier, H ;
Hoogenboom, R ;
Wouters, MEL ;
Schubert, US .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (09) :2913-2921
[10]   L-lactide polymerization utilizing a hydroxy-functionalized 3,6-bis(2-pyridyl)pyridazine as supramolecular (Co)initiator: Construction of polymeric [2x2] grids [J].
Hoogenboom, R ;
Wouters, D ;
Schubert, US .
MACROMOLECULES, 2003, 36 (13) :4743-4749