A readily-accessible (+)-sparteine surrogate

被引:204
作者
Dearden, MJ [1 ]
Firkin, CR [1 ]
Hermet, JPR [1 ]
O'Brien, P [1 ]
机构
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
关键词
D O I
10.1021/ja027774v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A "(+)-sparteine-like" chiral diamine, readily synthesized in three steps from (-)-cytisine, has been evaluated in four different asymmetric transformations; in each case, selectivity in an enantiocomplementary fashion to (-)-sparteine was observed. Copyright © 2002 American Chemical Society.
引用
收藏
页码:11870 / 11871
页数:2
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