Synthesis and X-ray crystal structure of [VCl3((-)-sparteine)] and [FeCl2((-)-sparteine)]

被引:19
作者
Lorber, C [1 ]
Choukroun, R [1 ]
Costes, JP [1 ]
Donnadieu, B [1 ]
机构
[1] CNRS UPR 8241, Chim Coordinat Lab, Equipe Precurseurs Mol & Mat, F-31077 Toulouse 04, France
关键词
(-)-sparteine; vanadium; chromium; iron;
D O I
10.1016/S1631-0748(02)01373-5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel complexes of vanadium(III), chromium(111) and iron(II) containing the alkaloid (-)-sparteine as a bidentate ligand have been prepared. Two of them, [VCl3((-)-sparteine)] and [FeCl2((-)-sparteine)], were characterised by X-ray diffraction. Known cobalt(Ill) and nickel(II) analogue complexes were prepared using the same procedure. (C) 2002 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.
引用
收藏
页码:251 / 255
页数:5
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