Behavior of P-Pt and P-Pd Bonds in Phosphido Complexes toward Electrophilic Fragments

被引：20

作者：

Alonso, Ester ^{[1
,2
]}

Fornies, Juan ^{[1
,2
]}

Fortuno, Consuelo ^{[1
,2
]}

Lledos, Agusti ^{[3
]}

Martin, Antonio ^{[1
,2
]}

Nova, Ainara ^{[3
]}

机构：

[1] Univ Zaragoza, CSIC, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

[3] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08193, Spain

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 16期

关键词：

BRIDGING DIPHENYLPHOSPHIDO LIGANDS; PALLADIUM(II)-PLATINUM(II) PENTAFLUOROPHENYL COMPLEXES; POTENTIAL BASIS-SETS; METAL-METAL; AB-INITIO; POLARIZATION FUNCTIONS; LINEAR OLIGOPHOSPHAALKANES; POLYNUCLEAR COMPLEXES; ELECTRONIC-STRUCTURES; MOLECULAR-STRUCTURES;

D O I：

10.1021/ic900415m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions between the unsaturated 30-valence-electron-count [(C6F5)(2)Pt(mu-PPh2)(2)M(PPh3)] (M = Pt, Pd) and [M'(OClO3)PPh3] (M' = Ag, Au) yield the cationic trinuclear [(C6F5)(2)Pt(mu-pph(2))(2)M(PPh3)(M'PPh3)][ClO4] (M = Pt, Pd; M'=Ag, Au), which displays Pt-M and M-M' bonds. The X-ray structures of the complexes reveal that the core of the molecules is planar and the Pt-M and M-M' distances point to the presence of Pt-M and M-M' bonds. A computational study on the formation of these complexes and the analysis of the interaction between the binuclear fragment [(C6F5)(2)Pt(mu-PPh2)(2)Pt(PPh3)] and the cation [Ag PPh3](+) has been carded out on the basis of density functional theory and shows that the Ag center interacts weakly with M and P (PPh2 ligand) atoms of the binuclear fragment.

引用

页码：7679 / 7690

页数：12

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