Interaction of NaI with solid water and methanol

被引：14

作者：

Hoefft, O. ^{[1
]}

Kahnert, U. ^{[1
]}

Bahr, S. ^{[1
]}

Kempter, V. ^{[1
]}

机构：

[1] Tech Univ Clausthal, Inst Phys & Phys Technol, D-38678 Clausthal Zellerfeld, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 34期

关键词：

D O I：

10.1021/jp0626014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction of NaI with amorphous solid water (ASW) and methanol (MeOH) has been investigated with metastable impact electron spectroscopy (MIES), UPS(HeI), and temperature programmed desorption (TPD). We have studied the electron emission from the ionization of the highest-lying states of H2O, CH3OH, and of 5pI. We have prepared NaI layers on ASW (MeOH) films at about 105 K and annealed them up to about 200 K. Surface segregation of iodide is observed in ASW, as predicted for NaI aqueous solutions. 1 On the other hand, surface segregation is not observed in MeOH, again as predicted for the interaction of NaI with liquid methanol. 2 Electronic properties (ionization potentials, optical band gaps) and water binding energies are reported and are analyzed on the basis of available DFT results for hydrated NaI clusters.(3)

引用

页码：17115 / 17120

页数：6

共 35 条

[31] Heterogeneous and multiphase chemistry in the troposphere [J].

Ravishankara, AR .

SCIENCE, 1997, 276 (5315) :1058-1065

[32]

Redhead P. A., 1962, Vacuum, V12, P203, DOI [10.1016/0042-207X(62)90978-8, DOI 10.1016/0042-207X(62)90978-8]

[33] Dissolution nature of cesium fluoride by water molecules [J].

Singh, NJ ;

Yi, HB ;

Min, SK ;

Park, M ;

Kim, KS .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (08) :3808-3815

[34] Electron binding energies of aqueous alkali and halide ions: EUV photoelectron spectroscopy of liquid solutions and combined ab initio and molecular dynamics calculations [J].

Winter, B ;

Weber, R ;

Hertel, IV ;

Faubel, M ;

Jungwirth, P ;

Brown, EC ;

Bradforth, SE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :7203-7214

[35] NEUTRON-DIFFRACTION STUDY ON CHLORIDE-ION SOLVATION IN WATER, METHANOL, AND N,N-DIMETHYLFORMAMIDE [J].

YAMAGAMI, M ;

WAKITA, H ;

YAMAGUCHI, T .

JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (18) :8174-8178

← 1 2 3 4 →