The fabrication of hollow spherical copper sulfide nanoparticle assemblies with 2-hydroxypropyl-β-cyclodextrin as a template under sonication

被引:63
作者
Xu, Jin-Zhong
Xu, Shu
Geng, Jun
Li, Gen-Xi
Zhu, Jun-Jie [1 ]
机构
[1] Nanjing Univ, Dept Chem, Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China
[2] Jiangsu Inst Educ, Dept Chem, Nanjing 210013, Peoples R China
基金
中国国家自然科学基金;
关键词
copper sulfide; 2-Hydroxypropyl-beta-cyclodextrin; hollow spherical structure; sonochemistry;
D O I
10.1016/j.ultsonch.2005.09.003
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
2-Hydroxypropyl-beta-cyclodextrin was used as a template to fabricate hollow spherical copper sulfide nanoparticle assemblies in the presence of sonication. The as-prepared spheres were uniform in shape and have well-defined shells composed of one-layered CuS nanoparticles. The interaction between the Cu ions and HP-beta-CD was confirmed by the FTIR. The effects of the sonication were studied and a possible self-assembly mechanism was discussed. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:451 / 454
页数:4
相关论文
共 22 条
[1]   Sonochemically produced ZnS-coated polystyrene core-shell particles for use in photonic crystals [J].
Breen, ML ;
Dinsmore, AD ;
Pink, RH ;
Qadri, SB ;
Ratna, BR .
LANGMUIR, 2001, 17 (03) :903-907
[2]  
Caruso F, 2001, ADV MATER, V13, P11, DOI 10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO
[3]  
2-N
[4]   Synthesis of novel copper sulfide hollow spheres generated from copper (II)-thiourea complex [J].
Chen, XY ;
Wang, ZH ;
Wang, X ;
Zhang, R ;
Liu, XY ;
Lin, WJ ;
Qian, YT .
JOURNAL OF CRYSTAL GROWTH, 2004, 263 (1-4) :570-574
[5]   Interfacial synthesis of hollow microspheres of mesostructured silica [J].
Fowler, CE ;
Khushalani, D ;
Mann, S .
CHEMICAL COMMUNICATIONS, 2001, (19) :2028-2029
[6]   Chromatographic determination of the association constant between 8-methoxypsoralen and modified β-cyclodextrin:: protective effect of hydroxypropyl-β-cyclodextrin on 8-methoxypsoralen toxicity in human keratinocytes [J].
Guillaume, Y ;
Andre, C ;
Simon, N ;
Gehin, A ;
Guyon, C ;
Thomassin, A ;
Ismaili, L ;
Aubin, F ;
Nicod, L .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2003, 798 (02) :217-222
[7]   CRYSTAL-STRUCTURE AND OPTICAL-PROPERTIES OF CD32S14(SC6H5)36.DMF4, A CLUSTER WITH A 15-ANGSTROM CDS CORE [J].
HERRON, N ;
CALABRESE, JC ;
FARNETH, WE ;
WANG, Y .
SCIENCE, 1993, 259 (5100) :1426-1428
[8]  
HUANG J, 2000, ADV MATER, V12, P1518
[9]   β-cyclodextrin controlled assembling nanostructures from gold nanoparticles to gold nanowires [J].
Huang, YJ ;
Li, D ;
Li, JH .
CHEMICAL PHYSICS LETTERS, 2004, 389 (1-3) :14-18
[10]   Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for Suzuki coupling reactions [J].
Kim, SW ;
Kim, M ;
Lee, WY ;
Hyeon, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (26) :7642-7643