First enantio-flexible fluorination reaction using metal-bis(oxazoline) complexes

被引:131
作者
Shibata, N [1 ]
Ishimaru, T [1 ]
Nagai, T [1 ]
Kohno, J [1 ]
Toru, T [1 ]
机构
[1] Nagoya Inst Technol, Nagare Coll, Grad Sch Engn, Dept Appl Chem, Nagoya, Aichi 4668555, Japan
关键词
fluorine; halogenation; nickel; copper; asymmetric catalysis;
D O I
10.1055/s-2004-829571
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first examples of an elective sense of enantioselectivity in enantioselective fluorination reaction using (S,S)-bis(oxazoline)-Ph complexed with Cu(II) or Ni(II) are described.
引用
收藏
页码:1703 / 1706
页数:4
相关论文
共 46 条
  • [11] An efficient enantioselective fluorination of various β-ketoesters catalyzed chiral palladium complexes
    Hamashima, Y
    Yagi, K
    Takano, H
    Tamás, L
    Sodeoka, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (49) : 14530 - 14531
  • [12] Hintermann L, 2000, ANGEW CHEM INT EDIT, V39, P4359, DOI 10.1002/1521-3773(20001201)39:23<4359::AID-ANIE4359>3.0.CO
  • [13] 2-P
  • [14] MULTIMACROCYCLIC COMPOUNDS .4. INTERNAL TRIMERISATION OF TRIPLE BONDS OF LINEAR TRIYNES ON A ZIEGLER CATALYST
    HUBERT, AJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (20): : 1984 - &
  • [15] Enantioselective halogenation reactions
    Ibrahim, H
    Togni, A
    [J]. CHEMICAL COMMUNICATIONS, 2004, (10) : 1147 - 1155
  • [16] Enantioselective Michael additions of nitromethane by a catalytic double activation method using chiral Lewis acid and achiral amine catalysts
    Itoh, K
    Kanemasa, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) : 13394 - 13395
  • [17] Chiral bis(oxazoline) copper(II) complexes: Versatile catalysts for enantioselective cycloaddition, aldol, Michael, and carbonyl ene reactions
    Johnson, JS
    Evans, DA
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) : 325 - 335
  • [18] Jorgensen KA, 2000, ANGEW CHEM INT EDIT, V39, P3558, DOI 10.1002/1521-3773(20001016)39:20<3558::AID-ANIE3558>3.0.CO
  • [19] 2-I
  • [20] Catalytic asymmetric addition reactions of carbonyls. A common catalytic approach
    Jorgensen, KA
    Johannsen, M
    Yao, SL
    Audrain, H
    Thorhauge, J
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (07) : 605 - 613