Opening a Can of Worm(-like Micelle)s: The Effect of Temperature of Solutions of Functionalized Dipeptides

被引:64
作者
Draper, Emily R. [1 ]
Su, Hao [2 ]
Brasnett, Christopher [3 ]
Poole, Robert J. [4 ]
Rogers, Sarah [5 ]
Cui, Honggang [2 ]
Seddon, Annela [3 ,6 ]
Adams, Dave J. [1 ]
机构
[1] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Johns Hopkins Univ, Whiting Sch Engn, Dept Chem & Biomol Engn, 3400 North Charles St, Baltimore, MD 21218 USA
[3] Univ Bristol, Sch Phys, HH Wills Phys Lab, Tyndall Ave, Bristol BS8 1TL, Avon, England
[4] Univ Liverpool, Sch Engn, Liverpool L69 3GH, Merseyside, England
[5] Rutherford Appleton Lab, ISIS Pulsed Neutron Source, Didcot OX11 0QX, Oxon, England
[6] Univ Bristol, Bristol Ctr Funct Nanomat, HH Wills Phys Lab, Tyndall Ave, Bristol BS8 1TL, Avon, England
基金
英国工程与自然科学研究理事会;
关键词
dipeptides; gels; low-molecular-weight gelators; micelles; theology; HYDROGELS; GELATORS; GELS; NAPHTHALENE; RHEOMETRY;
D O I
10.1002/anie.201705604
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple heat/cool cycle can be used to significantly affect the properties of a solution of a low-molecular-weight gelator at high pH. The viscosity and extensional viscosity are increased markedly, leading to materials with very different properties than when the native solution is used.
引用
收藏
页码:10467 / 10470
页数:4
相关论文
共 28 条
[1]   Supramolecular materials [J].
Amabilino, David B. ;
Smith, David K. ;
Steed, Jonathan W. .
CHEMICAL SOCIETY REVIEWS, 2017, 46 (09) :2404-2420
[2]  
Barnes J. F. H. H. A., 1989, RHEOLOGY SERIES, V3
[3]   The slow retraction method (SRM) for the determination of ultra-short relaxation times in capillary breakup extensional rheometry experiments [J].
Campo-Deano, Laura ;
Clasen, Christian .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 2010, 165 (23-24) :1688-1699
[4]   Linking micellar structures to hydrogelation for salt-triggered dipeptide gelators [J].
Cardoso, Andre Zamith ;
Mears, Laura L. E. ;
Cattoz, Beatrice N. ;
Griffiths, Peter C. ;
Schweins, Ralf ;
Adams, Dave J. .
SOFT MATTER, 2016, 12 (15) :3612-3621
[5]   Salt-induced hydrogels from functionalised-dipeptides [J].
Chen, Lin ;
McDonald, Tom O. ;
Adams, Dave J. .
RSC ADVANCES, 2013, 3 (23) :8714-8720
[6]   Salt-induced hydrogelation of functionalised-dipeptides at high pH [J].
Chen, Lin ;
Pont, Guillaume ;
Morris, Kyle ;
Lotze, Gudrun ;
Squires, Adam ;
Serpell, Louise C. ;
Adams, Dave J. .
CHEMICAL COMMUNICATIONS, 2011, 47 (44) :12071-12073
[7]   Effect of Molecular Structure on the Properties of Naphthalene-Dipeptide Hydrogelators [J].
Chen, Lin ;
Revel, Steven ;
Morris, Kyle ;
Serpell, Louise C. ;
Adams, Dave J. .
LANGMUIR, 2010, 26 (16) :13466-13471
[8]   Controlling the network type in self-assembled dipeptide hydrogels [J].
Colquhoun, Catherine ;
Draper, Emily R. ;
Schweins, Ralf ;
Marcello, Marco ;
Vadukul, Devkee ;
Serpell, Louise C. ;
Adams, Dave J. .
SOFT MATTER, 2017, 13 (09) :1914-1919
[9]   Two approaches for the engineering of homogeneous small-molecule hydrogels [J].
Ding, Baiyong ;
Li, Ying ;
Qin, Meng ;
Ding, Yin ;
Cao, Yi ;
Wang, Wei .
SOFT MATTER, 2013, 9 (18) :4672-4680
[10]   Nonlinear Effects in Multicomponent Supramolecular Hydrogels [J].
Draper, Emily R. ;
Wallace, Matthew ;
Schweins, Ralf ;
Poole, Robert J. ;
Adams, Dave J. .
LANGMUIR, 2017, 33 (09) :2387-2395