Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens

被引：23

作者：

Guillevic, MA

Light, ME

Coles, SJ

Gelbrich, T

Hursthouse, MB

Bruce, DW

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

[2] Univ Southampton, Dept Chem, EPSRC Crystallog Serv, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 09期

关键词：

D O I：

10.1039/a910273f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Seven anisotropic diimines and their corresponding dinuclear complexes of rhenium(I) have been synthesized. The crystal and molecular structures of one of the dimines and two of the complexes were determined. In common with related imine ligands which have been synthesized previously, the new diimines were mesomorphic showing smectic C and nematic phases and, in some cases, smectic I and crystal J phases. However, none of the orthometallated, dinuclear complexes showed any liquid crystal phases.

引用

页码：1437 / 1445

页数：9

共 20 条

[1]

[Anonymous], 1998, COLLECT DAT COLL SOF

[2] PENTACARBONYL(TETRAFLUOROBORATO)RHENIUM AND PENTACARBONYLMANGANESE AND REACTIONS THEREOF [J].